Do you like my blog? If you like, you can also browse other articles about this kind. category: chiral-catalyst. Thanks for taking the time to read the blog about 14187-32-7
In an article, published in an article, once mentioned the application of 14187-32-7, Name is Dibenzo-18-crown-6,molecular formula is C20H24O6, is a conventional compound. this article was the specific content is as follows.category: chiral-catalyst
Stability constants Kf(LK+) and Kf(LKX) = / at 25 deg in the dipolar aprotic solvents acetone (Me2CO), acetonitrile (MeCN), propylene carbonate (pc), N,N-dimethylformamide (HCONMe2), dimethyl sulfoxide (Me2SO), as well as in the alcohols, methanol (MeOH), isopropyl alcohol (PriOH), and butan-1-ol(BuOH) have been determined, L being bis(4,4′(5′)-t-butylbenzo-18-crown-6 (di(BuBo)-18-cr-6).This crown is considerably more lipophylic than is dibenzo-18-crown-6.Values of Kf(LKX) have been found from values of Kf(LK+), KA(KX) and KA(LKX).Transfer activity coefficients Me2COgammaSi have been calculated (based on the Parker proposal that gamma(Ph4As+) = gamma(BPh4-) between acetone and the various solvents used of K+, Br-, ClO4-, Pi- (picrate), LK+, KX, and LKX.It is found that K+ is more strongly solvated in Me2CO than in the other aprotic solvents of low donicity.The reverse is true between Me2CO and HCONMe2 or MeSO (even after correcting for the Born effect).
Do you like my blog? If you like, you can also browse other articles about this kind. category: chiral-catalyst. Thanks for taking the time to read the blog about 14187-32-7
Reference：
Chiral Catalysts,
Chiral catalysts – SlideShare