Reference of 1436-59-5, Chemistry can be defined as the study of matter and the changes it undergoes. You’ll sometimes hear it called the central science because it is the connection between physics and all the other sciences, starting with biology.1436-59-5, Name is cis-Cyclohexane-1,2-diamine, molecular formula is C6H14N2. In a patent, introducing its new discovery.
Homochiral pairs of vicinal diamines and vicinal diols form well- defined crystalline supramolecular assemblies (supraminols) asa result of mutual recognition. X-ray crystallographic analysis shows extensive hydrogen bonding between amine and alcohol groups that results in a hydrophilic inner core and hydrophobic outer peripheral units. The inner core consists of partially or fully hydrogen-bonded amine-alcohol interactions that lead to a pleated sheet- or ribbonlike secondary structure. The outer periphery consists of left- or right-handed helical strands of alternating diamine- diol units, depending on the sense of chirality of the diamine and the diol. High enantiomeric enrichment is possible when an enantiopure diamine and a racemic diol are allowed to interact resulting in a matched homochiral crystalline adduct. In one instance, the occlusion of a molecule of benzene within the assembly was observed. On the basis of competition experiments, some predictions can be made regarding the best matched pairs of diamines and diols, which we have termed supramolecular chirons.
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