Synthetic Route of 14187-32-7. Let’s face it, organic chemistry can seem difficult to learn. Especially from a beginner’s point of view. Like 14187-32-7, Name is Dibenzo-18-crown-6. In a document type is Article, introducing its new discovery.
In the two compounds (borohydrido)(1,4,7,10,13,16-hexaoxacyclooctadecane- kappa6O)potassium, [K(BH4)(C12H 24O6)], (I), and (borohydrido)(1,4,7,10,13,16-hexaoxa-2,3: 11,12-dibenzocyclooctadeca-2,11-diene-kappa6O)(tetrahydrofuran) potassium, [K(BH4)(C4H8O)(C20H 24O6)], (II), the K atom is bound to the six O atoms of the crown ether and to a tridentate borohydride group, with further coordination to a tetrahydrofuran molecule in (II). The alkali metal ion environment is thus distorted hexagonal-pyramidal in (I) and bipyramidal in (II).
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