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We present a novel methodology for the asymmetric synthesis of beta-mercaptolactones via isomerization of omega-hydroxy-alpha,beta- unsaturated thioesters by means of a bifunctional aminothiourea catalyst. The catalyst interacts with the substrate through the cooperative action of both a covalent bond at the amino group and noncovalent bonding at the thiourea group. The potential for an enantiodivergent synthesis could also be demonstrated by carrying out the reaction in a different solvent system.
But sometimes, even after several years of basic chemistry education,, 21436-03-3 it is not easy to form a clear picture on how they govern reactivity! Read on for other articles about 21436-03-3!
Reference£º
Chiral Catalysts,
Chiral catalysts – SlideShare