In an article, published in an article, once mentioned the application of 14098-44-3, Name is Benzo-15-crown-5,molecular formula is C14H20O5, is a conventional compound. this article was the specific content is as follows.SDS of cas: 14098-44-3
Ruthenium-benzocrownether complexes: Synthesis, structures, catalysis and immobilisation in ionic liquids
A facile pathway to [RuCl2(eta6-benzocrownether)] 2 complexes is described and crystal structures of the complexes [RuCl2(eta6-benzo-15-crown-5)]2 and [RuCl2(eta6-dibenzo-18-crown-6)]2 are reported. The complexes were derivatised with (1S,2R)-2-amino-1,2- diphenylethanol and evaluated in the enantioselective transfer-hydrogenation of acetophenone. The effect of complexation of different alkaline metals (Na, K, Cs) within the crown on the selectivity and reaction rate was studied. Interaction of a sulfonated phosphine ligand with the crown was probed by NOESY-NMR and utilisation of the crownether to serve as an anchor for catalyst immobilisation was investigated.
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Reference£º
Chiral Catalysts,
Chiral catalysts – SlideShare