The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.53152-69-5, Name is (1R,2R)-N1,N1,N2,N2-Tetramethylcyclohexane-1,2-diamine, molecular formula is C10H22N2. In a Article£¬once mentioned of 53152-69-5, Application In Synthesis of (1R,2R)-N1,N1,N2,N2-Tetramethylcyclohexane-1,2-diamine
The smaller, the better? How the aggregate size affects the reactivity of (trimethylsilyl)methyllithium
Weighting both the basicity and nucleophilicity of an organolithium compound is crucial for an effective use of these reagents in syntheses. To achieve this, an aggregate of optimal size and reactivity has to be formed by adding suitable donating agents. Against usual expectations, this is not inevitably the smallest possible aggregate. In this work, we show that the monomeric complex of (trimethylsilyl)methyllithium stabilized by the bidentate ligand (R,R)-TMCDA shows no significant reactivity. In contrast, two dimeric aggregates stabilized by monodentate quinuclidine were obtained, exhibiting enhanced reactivity compared to the parent compound and to the monomeric complex.
The reactant in an enzyme-catalyzed reaction is called a substrate. Enzyme inhibitors cause a decrease in the reaction rate of an enzyme-catalyzed reaction.I hope my blog about 53152-69-5 is helpful to your research., Application In Synthesis of (1R,2R)-N1,N1,N2,N2-Tetramethylcyclohexane-1,2-diamine
Reference£º
Chiral Catalysts,
Chiral catalysts – SlideShare