In an article, published in an article, once mentioned the application of 894493-95-9, Name is (1S,2S)-N1,N1-Dimethylcyclohexane-1,2-diamine,molecular formula is C8H18N2, is a conventional compound. this article was the specific content is as follows.Application In Synthesis of (1S,2S)-N1,N1-Dimethylcyclohexane-1,2-diamine
Asymmetric isomerization of omega-hydroxy-alpha,beta-unsaturated thioesters into beta-mercaptolactones by a bifunctional aminothiourea catalyst
We present a novel methodology for the asymmetric synthesis of beta-mercaptolactones via isomerization of omega-hydroxy-alpha,beta- unsaturated thioesters by means of a bifunctional aminothiourea catalyst. The catalyst interacts with the substrate through the cooperative action of both a covalent bond at the amino group and noncovalent bonding at the thiourea group. The potential for an enantiodivergent synthesis could also be demonstrated by carrying out the reaction in a different solvent system.
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Reference£º
Chiral Catalysts,
Chiral catalysts – SlideShare