In an article, published in an article, once mentioned the application of 7181-87-5, Name is 1,3-Dimethyl-1H-benzo[d]imidazol-3-ium iodide,molecular formula is C9H11IN2, is a conventional compound. this article was the specific content is as follows.Quality Control of: 1,3-Dimethyl-1H-benzo[d]imidazol-3-ium iodide
NHC-Palladium(II) Mononuclear and Binuclear Complexes Containing Phenylene-Bridged Bis(thione) Ligands: Synthesis, Characterization, and Catalytic Activities
A series of mono- and binuclear Pd(II) complexes with N-heterocyclic carbene (NHC) and phenylene-bridged bis(thione) (SCS) ligands were prepared and characterized by 1H and 13C NMR spectroscopy, IR, and mass spectrometry. The molecular structures of 1b, 2a, and 3b have been determined by the single-crystal X-ray diffraction method. The catalytic activities of the synthesized palladium complexes in the regioselective reduction of quinolines to the corresponding 1,2,3,4-tetrahydroquinolines were thoroughly investigated with ammonia-borane under mild reaction conditions. It is observed that the activities of the binuclear Pd(NHC) complexes were higher than those of the corresponding mononuclear complexes under the same conditions.
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Reference£º
Chiral Catalysts,
Chiral catalysts – SlideShare