Archives for Chemistry Experiments of 21436-03-3

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Related Products of 21436-03-3. Let¡¯s face it, organic chemistry can seem difficult to learn. Especially from a beginner¡¯s point of view. Like 21436-03-3, Name is (1S,2S)-Cyclohexane-1,2-diamine. In a document type is Article, introducing its new discovery.

[PtCl(eta1-CH2-CH2OR)(NN)] and [PtCl(eta2-CH2CH2)(NN)]+, NN = dinitrogen ligand, complexes. Sterical and electronic effects evidenced by NMR analysis

In this work we report on the synthesis of new [PtCl(eta2-CH2CH2)(NN)]+ and [PtCl(eta1-CH2-CH2OCH3)(NN)] complexes, with different NN dinitrogen ligands, i.e. ethylenediamine (en), R,R- and S,S-diaminocyclohexane (R,R- and S,S-chxn), R,R- and S,S-N,N,N?,N?-tetramethyl-1,2-diaminocyclohexane (R,R- and S,S-Me4chxn). In particular, the factors determining complex stability are highlighted, and discussed in relation to 1H, 13C and 195Pt NMR chemical shifts exhibited by different complexes bearing hindered or unhindered diamine or diimine ligands.

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Reference£º
Chiral Catalysts,
Chiral catalysts – SlideShare