Synthetic Route of 921-60-8, As an important bridge between the micro and macro material world, chemistry is one of the main methods and means for humans to understand and transform the material world. 921-60-8, Name is L-Glucose, SMILES is O=C[C@H]([C@@H]([C@H]([C@H](CO)O)O)O)O, belongs to chiral-catalyst compound. In a article, author is Cao, Yang, introduce new discover of the category.
The catalytic asymmetric 1,4-reduction of alpha-branched 2-vinylazaarenes by a SPINOL-derived borophosphate has been realized. A SPINOL-derived phosphoric acid is used to form a bifunctional phosphoryl boronate catalyst in situ in the presence of pinacolborane. This asymmetric 1,4-reduction reaction provides a convenient procedure to access chiral alkylated quinolines and benzothiazoles in high yields (up to 94%) and with good stereoselectivities (up to 98%).
Synthetic Route of 921-60-8, Each elementary reaction can be described in terms of its molecularity, the number of molecules that collide in that step. The slowest step in a reaction mechanism is the rate-determining step.you can also check out more blogs about 921-60-8.
Reference:
Chiral Catalysts,
,Chiral catalysts – SlideShare