Reactions catalyzed within inorganic and organic materials and at electrochemical interfaces commonly occur at high coverage and in condensed media, causing turnover rates to depend strongly on interfacial structure and composition, 80657-57-4, Name is (S)-Methyl 3-hydroxy-2-methylpropanoate, SMILES is O=C(OC)[C@@H](C)CO, in an article , author is Wu Dunqi, once mentioned of 80657-57-4, Recommanded Product: (S)-Methyl 3-hydroxy-2-methylpropanoate.
A new class of chiral tridentate P,N,N-donor pincer ligands bearing ltwo or three stereocenters, 1-(4,5-dihydrooxazol-2-y1)-N-(2-(diphenylphosphanypbenzyl)methanamines (oxpma), were synthesized starting from readily available amino acids in five or six steps. They were applied in palladium-catalyzed asymmetric allylic alkylation of allylic acetates to afford the desired products with high enantioselectivities (up to 96% ee).
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Reference:
Chiral Catalysts,
,Chiral catalysts – SlideShare