Chemistry is the science of change. But why do chemical reactions take place? Why do chemicals react with each other? The answer is in thermodynamics and kinetics, Product Details of 921-60-8, 921-60-8, Name is L-Glucose, SMILES is O=C[C@H]([C@@H]([C@H]([C@H](CO)O)O)O)O, belongs to chiral-catalyst compound. In a document, author is Ohtani, Shunsuke, introduce the new discover.
A chloro-substituted boron-fused azomethine complex (BAmCl) having a stereogenic boron center was synthesized for obtaining a luminescent chiral crystal. We succeeded in isolating the (R)- and (S)-enantiomers of BAmCl and preparing the homochiral polymorphic crystal, while we obtained the racemic crystal with rac-BAmCl. Single crystal X-ray diffraction analyses suggest that a variety of intermolecular interaction patterns and intrinsic flexibility of the molecular framework should play a significant role in stabilizing the homochiral crystal. We found the difference in molecular arrangements between the racemic and the homochiral crystals, and we observed distinctly different emission colors. In particular, we observed heat-initiated homogeneous racemization without the need for a solvent or catalyst in the molten state of the homochiral crystal (R)-BAmCl. Our results mean that chiral resolution of a flexible fused-skeleton having a stereogenic boron center can be a platform for creating luminescent polymorphic materials.
A reaction mechanism is the microscopic path by which reactants are transformed into products. Each step is an elementary reaction. In my other articles, you can also check out more blogs about 921-60-8. Product Details of 921-60-8.
Reference:
Chiral Catalysts,
,Chiral catalysts – SlideShare