Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, HPLC of Formula: C6H12O657-48-7, Name is (3S,4R,5R)-1,3,4,5,6-Pentahydroxyhexan-2-one, SMILES is [H][C@@](O)(CO)[C@@]([H])(O)[C@]([H])(O)C(=O)CO, belongs to chiral-catalyst compound. In a article, author is Han, Jung Tae, introduce new discover of the category.
The synthesis of gamma-chiral borylalkanes through copper-catalyzed enantioselective S(N)2 ‘-reduction of gamma,gamma-disubstituted allylic substrates and subsequent hydroboration was reported. A copper-DTBM-Segphos catalyst produced a range of gamma-chiral alkylboronates from easily accessible allylic acetate or benzoate with high enantioselectivities up to 99% ee. Furthermore, selective organic transformations of the resulting gamma-chiral alkylboronates generated the corresponding gamma-chiral alcohol, arene and amine compounds.
Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions. you can also check out more blogs about 57-48-7. HPLC of Formula: C6H12O6.
Reference:
Chiral Catalysts,
,Chiral catalysts – SlideShare