Archives for Chemistry Experiments of cis-Cyclohexane-1,2-diamine

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Diesters (1 and 3) of (1S,2S) and (1R,2R)-cyclohexanediol and diamides (2 and 4) of (1S,2S) and (1R,2R)-diaminocyclohexane with p-hydroxycinnamic and exhibit intense bisignate circular dichroism spectra in CH3OH: 1 Deltaepsilon+55 (323 nm), -34 (287 nm); 2 Deltaepsilon+75 (318 nm), -55 (281 nm) and in (CH3)2SO: 1 Deltaepsilon+53 (328 nm), -33 (292 nm); 2 Deltaepsilon+65 (319 nm), -50 (280 nm). Added NaOH causes a bathochromic shift of ~50 nm in CH3OH and ~80-90 nm in (CH3)2SO.

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Reference:
Chiral Catalysts,
Chiral catalysts – SlideShare