A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 250285-32-6, Name is 1,3-Bis(2,6-diisopropylphenyl)imidazolium chloride, molecular formula is C27H37ClN2. In a Article，once mentioned of 250285-32-6, name: 1,3-Bis(2,6-diisopropylphenyl)imidazolium chloride
Based on the synthesis of two new hexa-coordinate N-heterocyclic carbene (NHC) substituted precursors FeI2(CO)3(NHC) with NHC = IPr (1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene) (2) and NHC = SIPr (1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylide) (3) and two known complexes FeI2(CO)3SIMes, SIMes = (1,3-bis(2,4,6-trimethylphenyl)-imidazol-2-ylide) (1) and FeI2(CO)3IMe IMe = 1,3-bismethylimidazol-2-ylidene (4), four new mononuclear [Fe]-hydrogenase model complexes Fe(CO)2(NS)(NHC) (NS = aminothiophenol; 5, NHC = SIMes; 6, NHC = IPr; 7, NHC = SIPr; 8, NHC = IMe) were prepared by substitution of two iodine ligands with the help of dipotassium-aminothiophenol salt and subsequently the absence of a CO ligand. New complexes 2, 3 and 5-8 were fully structurally characterized by infrared spectroscopy (IR), elemental analysis, NMR spectroscopy, and X-ray crystallography. IR spectroscopy studies show that complexes 5-8 exhibit similar IR patterns and absorption wavelengths in terms of nu(CO) with the active site of [Fe]-hydrogenase. The facile protonation/deprotonation of the NS ligand of complexes 6 and 7 was disclosed with the assistance of IR spectroscopy. The NS ligand accepts a proton reversibly as an internal base, generating two protonated species, [Fe(CO)2IPr(H-NS)]+ and [Fe(CO)2SIPr(H-NS)]+, which play the same role with the intrinsic cysteine thiolate ligand in [Fe]-hydrogenase. DFT results showed that the N atom of the NS ligand is the thermodynamically active proton acceptor in acetone while the NS ligand is prone to be dually protonated first in the N atom and then the S atom in the gas phase. Complex 5 exhibited simultaneous protonation and the combination of CO, forming a new mer-tricarbonyl species in the presence of CO and HBF4. It showed easy reversible deprotonation and deprivation of CO with the assistance of t-BuOK or Et3N. Also, the electrochemical properties of these new pentacoordinate model complexes were explored through cyclic voltammetry, which enabled us to identify the contributions of different NHC ligands to the complexes’ redox properties.
Sometimes chemists are able to propose two or more mechanisms that are consistent with the available data.name: 1,3-Bis(2,6-diisopropylphenyl)imidazolium chloride, If a proposed mechanism predicts the wrong experimental rate law, however, the mechanism must be incorrect.Welcome to check out more blogs about 250285-32-6, in my other articles.