Archives for Chemistry Experiments of cis-Cyclohexane-1,2-diamine

If you are interested in 1436-59-5, you can contact me at any time and look forward to more communication.Application of 1436-59-5

Application of 1436-59-5. Let’s face it, organic chemistry can seem difficult to learn. Especially from a beginner’s point of view. Like 1436-59-5, Name is cis-Cyclohexane-1,2-diamine. In a document type is Article, introducing its new discovery.

Reaction of R,R:S,S-, R,R:R,R(or S,S:S,S)-bis(trans-cyclohexane-1,2-diamine)copper(II) with formaldehyde and nitroethane in aqueous base yields the macrocyclic molecular cation (4,15-dimethyl-4,15-dinitro-2,6,13,17-tetraazatricyclo<16.4.0.07,12>docosane)copper(II) with two -NH-CH2-C(Me)(NO2)-CH2-NH- links completing the macrocycle, as well as the molecular cation copper(II) with a single such link inserted.The rigid polycylic macrocycle, based on a 14-membered tetraazacycloalkane (cyclam) frame, may exist as a number of isomers.Spectroscopic and chiroptical properties of the isolated complexes are reported.Reduction of the nitro groups with zinc in aqueous acid produces the corresponding molecules with primary amine (or ammonium) pendants in good yield, as metal-free hydrochloride salts.

If you are interested in 1436-59-5, you can contact me at any time and look forward to more communication.Application of 1436-59-5

Reference：
Chiral Catalysts,
Chiral catalysts – SlideShare