53152-69-5, Name is (1R,2R)-N1,N1,N2,N2-Tetramethylcyclohexane-1,2-diamine, molecular formula is C10H22N2, belongs to chiral-catalyst compound, is a common compound. In a patnet, once mentioned the new application about 53152-69-5, Product Details of 53152-69-5
The preparation of aminomethyl functionalised silanes based on the alpha-lithiated amine, (1R,2R)-N,N,N?,N?-tetramethylcyclohexane-1, 2-diamine [(R,R)-TMCDA] is reported. This methodology can be applied for the synthesis of mono-aminomethyl substituted systems, but most remarkably also for di- and trifunctionalised compounds. The trapping of the lithiated amine is accompanied by transmetallation reactions resulting in the formation of (silylmethyl)silanes depending on the reaction temperature. The zinc(ii) halide complexes of the mono-functionalised systems show the formation of exclusively one configuration of the stereogenic nitrogen atom, in which the spatially more demanding substituent exhibits the pseudo-equatorial position. The di- and trifunctionalised systems feature high sensitivity towards Si-C bond cleavage under re-formation of the (R,R)-TMCDA fragment. The Royal Society of Chemistry 2012.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Product Details of 53152-69-5. In my other articles, you can also check out more blogs about 53152-69-5