New explortion of [1,1′-Binaphthalene]-2,2′-diamine

Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.category: chiral-catalyst. In my other articles, you can also check out more blogs about 4488-22-6

A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 4488-22-6, Name is [1,1′-Binaphthalene]-2,2′-diamine, molecular formula is C20H16N2. In a Article,once mentioned of 4488-22-6, category: chiral-catalyst

A series of zinc complexes based on asymmetrical N,N,O-tridentate ligands were prepared via binaphthyl diamine derivatives. These complexes were characterized and employed as catalysts in lactide polymerization. The X-ray diffraction analyses revealed that molecular structures of 1b and 2b were mononuclear complexes with zinc atoms in distorted octahedral geometries. Upon co-catalysis with isopropanol, complex 2a showed the highest activity among these zinc complexes for the ring-opening polymerization of l-lactide, and complex 3a exhibited the highest stereoselectivity for the ring-opening polymerization of rac-lactide affording substantially isotactic polylactide (PLA) with a Pm of 0.62. The polymerization kinetics using 2a as a catalyst was studied in detail. The kinetics of the polymerization results revealed that the rates of polymerization were first-order both in the monomer and the catalyst, and there was a linear relationship between the l-LA conversion and the number-average molecular weight of PLA with a narrow molecular distribution (1.07-1.17). The activation energy (31.49 kJ mol -1) was deduced according to the Arrhenius equation.

Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.category: chiral-catalyst. In my other articles, you can also check out more blogs about 4488-22-6

Reference:
Chiral Catalysts,
Chiral catalysts – SlideShare