Extracurricular laboratory:new discovery of 1,4,7,10,13-Pentaoxacyclopentadecane

The reactant in an enzyme-catalyzed reaction is called a substrate. Enzyme inhibitors cause a decrease in the reaction rate of an enzyme-catalyzed reaction.I hope my blog about 33100-27-5 is helpful to your research., Safety of 1,4,7,10,13-Pentaoxacyclopentadecane

The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.33100-27-5, Name is 1,4,7,10,13-Pentaoxacyclopentadecane, molecular formula is C10H20O5. In a Article,once mentioned of 33100-27-5, Safety of 1,4,7,10,13-Pentaoxacyclopentadecane

Fluorofluorenes [1,2,3,4,5,6,7,8-octafluoro-9-(pentafluorophenyl)-9H- fluorene (OFPF), 1,2,3,4,5,6,7,8-octafluoro-9-(2,4-trifluoromethylphenyl)-9H- fluorene (OFTF), and 1,2,3,4,5,6,7,8-octafluorofluorene (OFF)] react with sodium hydride or with lithium alkyls to give fluorofluorenyl anions which have been characterized in solution by 19F NMR spectroscopy. OFPF is deprotonated by ethylenediamine, by HMPT and by 1,7-diazo-bicyclo(5,4)-undec-7- ene (DBU), as shown by 1H and 19F NMR spectrometry. The new compound [rac-ethylene-bis(eta5-4,5,6,7-tetrahydroindenyl)] diallylzirconium(IV) (ZRAL), as prepared from [rac-ethylene- bis(eta5-4,5,6,7-tetrahydroindenyl)]dichloridezirconium(IV) and allylmagnesium chloride, undergoes allyl abstraction with OFPF, CPh 3[B(C6F5)4], and B(C 6F5)3 forming zirconium-containing cations, as established by 1H and 19F NMR spectrometry. Toluene/pentafluoroanisole solutions of the fluorinated anions, in combination with ZRAL, catalyze the polymerization of ethylene, with an activity comparable to that of MAO or CPh3[B(C6F5)4], a remarkable increase of activity being observed with the ZRAL/OFPF system.

The reactant in an enzyme-catalyzed reaction is called a substrate. Enzyme inhibitors cause a decrease in the reaction rate of an enzyme-catalyzed reaction.I hope my blog about 33100-27-5 is helpful to your research., Safety of 1,4,7,10,13-Pentaoxacyclopentadecane

Reference:
Chiral Catalysts,
Chiral catalysts – SlideShare