Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 1436-59-5, Name is cis-Cyclohexane-1,2-diamine, Quality Control of: cis-Cyclohexane-1,2-diamine.
The new three-dimensional thioantimonate [Fe(C6H 14N2)2][Sb6S10] was obtained under solvothermal conditions. The compound crystallizes in space group P1 with a = 6.174(4), b = 9.679(2), c = 12.772(3) A, alpha = 72.08(3), beta = 88.15(3), gamma = 89.51(3), Z = 2. Trigonal pyramidal [SbS3] units and [SbS4] groups are joined to form a two-dimensional [Sb6S10]2- layer. The in-situ formed [Fe(C6H14N2)2]2+ complexes act like pillars joining the layers into a three-dimensional framework through Fe-S bonds. The Fe-S bond lengths are long which may be caused by a pronounced Jahn-Teller distortion. The optical bandgap of 2.0 eV is in agreement with the brownish color of the compound. The Mossbauer spectrum shows a doublet with an isomer shift typical for Fe2+ in the high spin state. In the Raman spectrum the Sb-S stretching modes of the [SbS3] and [SbS 4] groups can be distinguished. Upon heating in nitogen the compound is decomposed in one step yielding Sb2S3 and FeSb 2S4.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Quality Control of: cis-Cyclohexane-1,2-diamine. In my other articles, you can also check out more blogs about 1436-59-5