Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 33100-27-5, Name is 1,4,7,10,13-Pentaoxacyclopentadecane, Application In Synthesis of 1,4,7,10,13-Pentaoxacyclopentadecane.
Equilibrium constants and enthalpies of hydrogen-bond formation of m-cresol to various cyclic (crown) and acyclic polyethers have been determined in benzene solvent.Equilibrium constants indicated no evidence for an operative macrocyclic effect; the relationship between the increasing size of the equilibrium constant and the number of ether oxygens was rationalized with a simple statistical thermodynamic model.Enthalpies of interactions ranged between -19 and -23 kJ*mol-1.In agreement with PCILO calculations, enthalpies of interaction were essentially independent of the number of oxygen atoms in the ether; no significant difference in enthalpies of interaction between cyclic and acyclic ethers was found. Key Words: Hydrogen bonds; crown ethers; m-cresol.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Application In Synthesis of 1,4,7,10,13-Pentaoxacyclopentadecane. In my other articles, you can also check out more blogs about 33100-27-5