Synthetic Route of 14098-44-3. Let’s face it, organic chemistry can seem difficult to learn. Especially from a beginner’s point of view. Like 14098-44-3, Name is Benzo-15-crown-5. In a document type is Article, introducing its new discovery.
The title compounds, [Li(C14H20O5)(H2O)] 2[Cu4I6]· -2C14H20O5, [Cs(C14H20O5)2]2[Cu 4I6] and [Na2(C12H24-O6)2(H 2O)3][Cu4I6], respectively, all show similar [Cu4I6]2- clusters disordered about a center of symmetry. The Cu atoms are three-coordinate, with an average Cu-I distance of 2.596 (3) A. Alkali-bound crown-ether groups serve as counter-ions. The three solid materials display identical emission in the visible when excited in the ultraviolet. Calculations of the atomic contributions to frontier orbitals show the highest occupied molecular orbital (HOMO) to be based primarily on contributions from four of the six I atoms and the lowest unoccupied molecular orbital (LUMO) to be primarily copper-based and involving contributions from the four Cu atoms.
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