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The formation of complexes between some amino acids and the ligand dibenzo-18-crown-6 was studied using a new spectrophotometric method. From the increase in solubility of the ligand the stability constants can be calculated under some assumptions. Using this method it is possible to measure the interactions between host and guest molecules by using very small amounts of the host molecules only. The stability of the so-formed complexes depends mainly upon the number of CH2 groups between the amino and carboxylic groups of the amino acid under study.
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