In an article, published in an article, once mentioned the application of 33100-27-5, Name is 1,4,7,10,13-Pentaoxacyclopentadecane,molecular formula is C10H20O5, is a conventional compound. this article was the specific content is as follows.Formula: C10H20O5
The interaction of iron(III) halides with 18-crown-6 or 15-crown-5 ethers has led to the isolation of several complexes, two of which, [FeCl3(H2O)2](15-crown-5) and H(FeBr4)(15-crown-5)2(H2O)2, yielde crystals suitable for single crystal X-ray structural analysis. The chloro complex crystallizes in the monoclinic P21 (No.4) space group with Z=2, a=8.574(1), b=13.714(2), c=8.223(1) A, beta=107.9°. The crystals contain trigonal bipyramidal [FeCl3(H2O)2] moieties hydrogen bonded to a partially disordered 15-crown-5 ether to form a polymeric chain oriented along the crystallographic c-axis. The bromo complex crystallizes in the cubic FD3- (No.203) space group with Z=8, a=19.500(2) A. The compound contains tetrahedral FeBr4(1-) anions which have no bonding interaction with the 15-crown-5 ether, which simply acts as a dielectric medium to separate the anions. A study of the thermal decomposition of the compoundswas performed by thermogravimetric analysis. IR and Moessbauer spectral measurements indicate that the decomposition products are water, acetal dehyde, dioxane, chlorine or bromine, carbon dioxide, carbon monoxide, and mixtures of hydrated iron(II) halides and iron oxides.
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