Recommanded Product: 2-Chloroethyl acetate. Aromatic compounds can be divided into two categories: single heterocycles and fused heterocycles. Compound: 2-Chloroethyl acetate, is researched, Molecular C4H7ClO2, CAS is 542-58-5, about The preparation and structural elucidation of uranium(VI) complexes and salts of the phosphorus ylides Ph3PCHCOPh, Ph3PC(COMe)(COPh) and Ph3PCHCOOCH2CH3. Author is Spencer, Elinor C.; Kalyanasundari, Balasubramanian; Mariyatra, Mahimaidoss Baby; Howard, Judith A. K.; Panchanatheswaran, Krishnaswamy.
The reaction in methanol of the phosphorus ylides Ph3PCHCOPh, benzoylmethylenetriphenylphosphorane (BPPY), and Ph3PC(COMe)(COPh), α-acetyl-α-benzoylmethylenetriphenylphosphorane (ABPPY), with UO2(NO3)2·6H2O at 273 K gives O-coordinated bis(ylide)-uranium(VI) complexes [UO2(ylide)2(NO3)2], whereas the reaction of BPPY and UO2(NO3)2·6H2O under reflux in benzene yields [H-BPPY]2+[U2O4(NO3)4(OH)2]2-. The reaction of Ph3PCHCOOCH2CH3, ethoxycarbonylmethylenetriphenylphosphorane (EPPY), with UO2(CH3COO)2·2H2O produces [H-EPPY]+[UO2(CH3COO)3]-. The structures of the free ylides ABPPY and EPPY are also discussed.
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