In organic chemistry, atoms other than carbon and hydrogen are generally referred to as heteroatoms. The most common heteroatoms are nitrogen, oxygen and sulfur. Now I present to you an article called A Ni3O-cluster based porous MOF for catalytic conversion of CO2 to cyclic carbonates, published in 2019-08-31, which mentions a compound: 931-40-8, mainly applied to nickel hydroxy aqua silanetriyltriisophthalato complex catalyst preparation crystal structure; gas adsorption nickel hydroxy aqua silanetriyltriisophthalato complex; cycloaddition catalyst nickel hydroxy aqua silanetriyltriisophthalato complex, Application In Synthesis of 4-(Hydroxymethyl)-1,3-dioxolan-2-one.
A novel Ni3O-based MOF, {[Ni3HL(μ3-OH)(H2O)2]•3(H2O)•DMA}n (1), was constructed based on an organosilicon hexacarboxylic acid linker of 5,5′,5”-(methylsilanetriyl)triisophthalic acid (H6L). In this structure, the deprotonated carboxylate groups assemble with trinuclear metal cluster nodes to give a 6-connected uninodal net. It possesses open channels and rich metal sites, and displays CO2 adsorption behavior. Further investigations indicate that the compound is catalytically effective for the cyclic carbonates by cycloaddition of CO2 to epoxides. Besides, the catalyst could be reused 5 times with no significant loss of catalytic activity and without structural deterioration.
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