A new application about 13811-71-7

Synthetic Route of 13811-71-7, Because enzymes can increase reaction rates by enormous factors and tend to be very specific, typically producing only a single product in quantitative yield, they are the focus of active research.you can also check out more blogs about 13811-71-7.

Synthetic Route of 13811-71-7, Enzymes are biological catalysts that produce large increases in reaction rates and tend to be specific for certain reactants and products. 13811-71-7, Name is (2S,3S)-Diethyl 2,3-dihydroxysuccinate, SMILES is O=C(OCC)[C@@H](O)[C@H](O)C(OCC)=O, belongs to chiral-catalyst compound. In a article, author is Li, Guozhu, introduce new discover of the category.

A new class of chiral cyclopentadienyl rhodium(I) complexes (CpRhI) bearing C-2-symmetric chiral bridged-ring-fused Cp ligands was prepared. The complexes were successfully applied to the asymmetric C-H activation reaction ofN-methoxybenzamides with quinones, affording a series of chiral hydrophenanthridinones in up to 82 % yield with up to 99 %ee. Interestingly, structure analysis reveals that the side wall of the optimal chiral CpRh(I)catalyst is vertically more extended, horizontally less extended, and closer to the metal center in comparison with the classic binaphthyl and spirobiindanyl CpRh(I)complexes, and may thus account for its superior catalytic performance.

Synthetic Route of 13811-71-7, Because enzymes can increase reaction rates by enormous factors and tend to be very specific, typically producing only a single product in quantitative yield, they are the focus of active research.you can also check out more blogs about 13811-71-7.

Reference:
Chiral Catalysts,
,Chiral catalysts – SlideShare