14187-32-7, Name is Dibenzo-18-crown-6, molecular formula is C20H24O6, belongs to chiral-catalyst compound, is a common compound. In a patnet, once mentioned the new application about 14187-32-7, Safety of Dibenzo-18-crown-6
A tricarboxylated PtCl(terpyridine) derivative exhibiting pH-dependent photocatalytic activity for H2 evolution from water
The first negatively charged PtCl(tpy) (tpy = 2,2?:6?,2??-terpyridine) derivative, formulated as Na2[PtCl(tctpy)]¡¤5H2O (tctpy = 2,2?:6?,2??-terpyridine-4,4?,4??-tricarboxylate), was prepared, characterized, and investigated in detail for its activity as a single-component photocatalyst that drives water reduction to H2 in the presence of a sacrificial electron donor (EDTA). This compound was confirmed to exist in its fully deprotonated form [PtCl(tctpy)]2- in aqueous media at pH > 4.4. Despite its dianionic character, [PtCl(tctpy)]2- was found to form a specific adduct with anionic EDTA (i.e., YH22- and YH3-, where YH4 is a fully protonated form of EDTA), enabling reductive quenching of the triplet metal-to-ligand charge transfer excited state within the adduct, leading to subsequent electron transfer steps correlated with Pt(ii)-catalyzed H2 evolution from water. Electrochemical studies also reveal that the compound exhibits a unique pH-dependent first reduction (i.e., tctpy-centered reduction), leading to our realization of the first example of a Pt(ii)-based molecular system that photocatalyzes the H2 evolution reaction accompanied by a ligand-based proton-coupled electron transfer (PCET) process.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Safety of Dibenzo-18-crown-6. In my other articles, you can also check out more blogs about 14187-32-7
Reference£º
Chiral Catalysts,
Chiral catalysts – SlideShare