Chemistry is the experimental and theoretical study of materials on their properties at both the macroscopic and microscopic levels. 67579-81-1, Name is trans-N1,N2-Dimethylcyclohexane-1,2-diamine, molecular formula is C8H18N2. In an article, author is Guan, Wen-Li,once mentioned of 67579-81-1, Safety of trans-N1,N2-Dimethylcyclohexane-1,2-diamine.
In recent years, with the development of supramolecular chemistry, stimuli-responsive supramolecular gels have attracted more and more researchers’ interests. Among these gels, redox-responsive supramolecular gels have shown nice application prospects because of their reversible redox-responsiveness and electric field responsiveness. Owing to the existence of redox-reacting site, for example, radical, ferrocene, iron ions, ammonium salt, iodine molecules, pi-pi system and so on, the redox-responsive gel generally could change the gelator or the self-assembling state under the redox conditions. Therefore, the responsiveness of this kind of gel included phase changes, colour changes, fluorescence response or chiral structure changes induced by a redox reaction. The redox-responsive supramolecular gels, as a kind of smart material, could be used in storing energy, recognition, bioimaging, biomedical, fluorescent sensor, self-erasing ink, drug delivery, chiral catalyst, etc. In this review, we present the research progress of the redox-responsive supramolecular gel in recent years according to the gelator structures including alkyl chain-based redox gels, steroidal derivative-based redox gels, metal-organic compound-based redox gels, amino acid or peptide-based redox gels, macrocycle derivatives-based gels and pi-gels. It is anticipated that more and more efficiency redox-responsive supramolecular gels with novel redox mechanisms and useful applications will be developed in the near future.
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Reference:
Chiral Catalysts,
,Chiral catalysts – SlideShare