Application of 33100-27-5. Let’s face it, organic chemistry can seem difficult to learn. Especially from a beginner’s point of view. Like 33100-27-5, Name is 1,4,7,10,13-Pentaoxacyclopentadecane. In a document type is Article, introducing its new discovery.
In contrast to the neutral macrocycle [UN2(N,C)] (1) [N* = N(SiMe3)3; N,C = CH2SiMe 2N(SiMe3)] which was quite inert toward I2, the anionic bismetallacycle [NaUN(N,C)2] (2) was readily transformed into the enlarged monometallacycle [UN(N,N)I] (4) [N,N = (Me3Si) NSiMe2CH2CH2SiMe2N(SiMe 3)] resulting from C-C coupling of the two CH2 groups, and [NaUN(N,O)2] (3) [N,O = OC(=CH2)SiMe 2N(SiMe3)], which is devoid of any U-C bond, was oxidized into the UV bismetallacycle [Na{UN(N,O)2} 2(mu-I)] (5). Sodium amalgam reduction of 4 gave the U III compound [UN(N,N)] (6). Addition of MN3 or MCN to the (N,C), (N,N), and (N,O) metallacycles 1, 4, and 5 led to the formation of the anionic azide or cyanide derivatives M[UN2(N,C)(N3)] [M = Na, 7a or Na(15-crown-5), 7b], M[UN2(N,C)(CN)] [M = NEt4, 8a or Na(15-crown-5), 8b or K(18-crown-6), 8c], M[UN(N,N)(N3) 2] [M = Na, 9a or Na(THF)4, 9b], [NEt4][UN(N,N) (CN)2] (10), M[UN(N,O)2(N3)] [M = Na, 11a or Na(15-crown-5), 11b], M[UN(N,O)2(CN)] [M = NEt4, 12a or Na(15-crown-5), 12b]. In the presence of excess iodine in THF, the cyanide 12a was converted back into the iodide 5, while the azide 11a was transformed into the neutral UV complex [U(N{SiMe3}SiMe2C{CHI}O) 2I(THF)] (13). The X-ray crystal structures of 4, 7b, 8a-c, 9b, 10, 12b, and 13 were determined.
If you are interested in 33100-27-5, you can contact me at any time and look forward to more communication.Application of 33100-27-5