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Intercepting low oxidation state main group hydrides with a nucleophilic N-heterocyclic olefin

The N-heterocyclic olefin, IPrCH2 (IPr = [(HCNDipp) 2C], Dipp = 2,6-iPr2C6H3) has been demonstrated to be of sufficient Lewis basicity to stabilize main group hydrides in unusually low oxidation states.

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Reference£º
Chiral Catalysts,
Chiral catalysts – SlideShare