A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 79-33-4, Name is L-Lactic acid, molecular formula is C3H6O3. In an article, author is Wang, Qiang,once mentioned of 79-33-4, Recommanded Product: L-Lactic acid.
1,1-Disubstituted styrenes with internal oxygen and nitrogen nucleophiles undergo oxidative fluorocyclization reactions with in situ generated chiral iodine(III)-catalysts. The resulting fluorinated tetrahydrofurans and pyrrolidines contain a tertiary carbon-fluorine stereocenter. Application of a new 1-naphthyllactic acid-based iodine(III)-catalyst allows the control of tertiary carbon-fluorine stereocenters with up to 96% ee. Density functional theory calculations are performed to investigate the details of the mechanism and the factors governing the stereoselectivity of the reaction.
Interested yet? Keep reading other articles of 79-33-4, you can contact me at any time and look forward to more communication. Recommanded Product: L-Lactic acid.
Reference:
Chiral Catalysts,
,Chiral catalysts – SlideShare