1436-59-5, In an article, published in an article,authors is Bennov, Rachel R., once mentioned the application of 1436-59-5, Name is cis-Cyclohexane-1,2-diamine,molecular formula is C6H14N2, is a conventional compound. this article was the specific content is as follows.
Molybdenum complexes of chiral C2-symmetric picchxn-type ligands: Synthesis, characterization, and structural studies
A series of molybdenum complexes based on chiral C2-symmetric picchxn-type ligands (N4 ligands, defined as trans-N,N?-bis(heterocycl-2-ylmethyl)-1,2-diaminocyclohexanes) has been synthesized and characterized. Reported and novel picchxn-type ligands form (kappa3-N4)Mo(CO)3, [(kappa4-N4)Mo(NO)(CO)]PF6, and [(kappa4-N4)Mo(NO)X]PF6 (X = Br, I) compounds. Multiple tridentate (kappa3) and tetradentate (kappa4) ligand configurations were observed, and the favored kappa4 configuration was found to vary with N4 heterocycle identity. Heterocycle variation allowed for directed modification of the molybdenum electronic characteristics, but none of the studied {(kappa4-N4)Mo(NO)}+ fragments was found to be a suitable pi-base for dearomatization chemistry. The crystal structures of eight molybdenum complexes with picchxn-type ligands were determined.
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Reference£º
Chiral Catalysts,
Chiral catalysts – SlideShare