Synthetic Route of 14187-32-7. Let’s face it, organic chemistry can seem difficult to learn. Especially from a beginner’s point of view. Like 14187-32-7, Name is Dibenzo-18-crown-6. In a document type is Article, introducing its new discovery.
The respective dicarboxylic acids were obtained by the reaction of glycolic, beta-phenyllactic, and thioglycolic acids with diglycolic anhydride.Thirteen new macrocyclic esters were obtained by the reaction of the chlorides of these acids with polyethylene glycols under the conditions of high dilution.The stability constants of the complexes of these compounds with potassium and sodium cations in alcohol were determined by a polarographic method.It was established that certain crown ether triones exhibit appresiable sodium/potassium selectivity.
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