Synthetic Route of 14098-44-3, Catalysts are substances that increase the reaction rate of a chemical reaction without being consumed in the process. 14098-44-3, Name is Benzo-15-crown-5, molecular formula is C14H20O5. In a Article,once mentioned of 14098-44-3
Herein, we report the synthesis and molecular structure of the mono- and dianionic aromatic molecules [(B15C5-kappa5O)2K+](LDOPT-) (1) and [(B15C5-kappa5O)2K+]2(LDOPT2-)THFsolv (2) derived from the parent aromatic polyhydrocarbon 5,6:11,12-di-o-phenylenetetracene (DOPT, LDOPT) by a controlled stepwise one and two electron chemical reduction. The effect of single and double electron charge transfer to a polycondensed aromatic hydrocarbon (PAH) without any disturbing influence of an associated metal cation has been demonstrated. This was achieved by fully sandwiching the cationic K+ counterions between two benzo-15-crown-5-ether (B15C5) ligands resulting in a fully encapsulating (kappa10O) geometry which ensures a complete separation of the K+ counterions and the bare anionic PAH species [LDOPT-] and [LDOPT2-]. The structural changes accompanied by the stepwise reduction from LDOPT to [LDOPT-] to [LDOPT2-] are discussed and compared to earlier predictions based on density functional theory (DFT) as well as the results of previous studies of alkaline metal cationic PAH anion interactions of DOPT in which only a partial metal cation encapsulation has been achieved so far.
The proportionality constant is the rate constant for the particular unimolecular reaction. the reaction rate is directly proportional to the concentration of the reactant. I hope my blog about 14098-44-3 is helpful to your research., Synthetic Route of 14098-44-3
Reference:
Chiral Catalysts,
Chiral catalysts – SlideShare