Related Products of 33100-27-5. Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 33100-27-5, Name is 1,4,7,10,13-Pentaoxacyclopentadecane
The synthesis of the first linear coordinated CuIIcomplex Cu{N(SiMe3)Dipp}2(1 Dipp=C6H5-2,6Pri2) and its CuIcounterpart [Cu{N(SiMe3)Dipp}2]?(2) is described. The formation of 1 proceeds through a dispersion force-driven disproportionation, and is the reaction product of a CuIhalide and LiN(SiMe3)Dipp in a non-donor solvent. The synthesis of 2 is accomplished by preventing the disproportionation into 1 by using the complexing agent 15-crown-5. EPR spectroscopy of 1 provides the first detailed study of a two-coordinate transition-metal complex indicating strong covalency in the Cu?N bonds.
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