Application of 21436-03-3. Let’s face it, organic chemistry can seem difficult to learn. Especially from a beginner’s point of view. Like 21436-03-3, Name is (1S,2S)-Cyclohexane-1,2-diamine. In a document type is Article, introducing its new discovery.
The application of exciplex energy has become a unique way to achieve organic light-emitting diodes (OLEDs) with high efficiencies, low turn-on voltage, and low roll-off. Novel delta-carboline derivatives with high triplet energy (T1 ? 2.92 eV) and high glass transition temperature (Tg ? 153 C) were employed to manipulate exciplex emissions in this paper. Deep blue (peak at 436 nm) and pure blue (peak at 468 nm) thermally activated delayed fluorescence (TADF) of exciplex OLEDs were demonstrated by utilizing them as emitters with the maximum current efficiency (CE) of 4.64 cd A-1, power efficiency (PE) of 2.91 lm W-1, and external quantum efficiency (EQE) of 2.36%. Highly efficient blue phosphorescent OLEDs doped with FIrpic showed a maximum CE of 55.6 cd A-1, PE of 52.9 lm W-1, and EQE of 24.6% respectively with very low turn on voltage at 2.7 V. The devices still remain high CE of 46.5 cd A-1 at 100 cd m-2, 45.4 cd A-1 at 1000 cd m-2 and 42.3 cd A-1 at 5000 cd m-2 with EQE close to 20% indicating low roll-off. Manipulating blue exciplex emissions by chemical structure gives an ideal strategy to fully utilize all exciton energies for lighting of OLEDs.
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