Reference of 33100-27-5. Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 33100-27-5, Name is 1,4,7,10,13-Pentaoxacyclopentadecane
Hydrogen Peroxide Coordination to Cobalt(II) Facilitated by Second-Sphere Hydrogen Bonding
M(H2O2) adducts have been postulated as intermediates in biological and industrial processes; however, only one observable M(H2O2) adduct has been reported, where M is redox-inactive zinc. Herein, direct solution-phase detection of an M(H2O2) adduct with a redox-active metal, cobalt(II), is described. This CoII(H2O2) compound is made observable by incorporating second-sphere hydrogen-bonding interactions between bound H2O2and the supporting ligand, a trianionic trisulfonamido ligand. Thermodynamics of H2O2binding and decay kinetics of the CoII(H2O2) species are described, as well as the reaction of this CoII(H2O2) species with Group 2 cations.
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Chiral Catalysts,
Chiral catalysts – SlideShare