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Helicale Komplexliganden – Kationselektivitaet, Cu(1+)-Spezifitaet, chiroptische und Redox-Eigenschaften
The optically active alpha-pyridyl-substituted diazocines 4 and 7 have been synthesized.They exhibit high rotation values and high optical stabilities.The helices 3 and 5 unexpectedly are highly Cu(I) selective chiral ligands.The CD spectra are strongly cation dependent.Cyclic voltammetry reveals strong differences between 4 and its methyl-substituted analogue 5 as to their Cu(1+) complexes.
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Chiral Catalysts,
Chiral catalysts – SlideShare