Awesome and Easy Science Experiments about cis-Cyclohexane-1,2-diamine

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Reference of 1436-59-5, An article , which mentions 1436-59-5, molecular formula is C6H14N2. The compound – cis-Cyclohexane-1,2-diamine played an important role in people’s production and life.

A new synergistic multicomponent organogelator liquid system (MOGLS) was discovered during the standard protocol of tartaric acid-mediated racemic resolution of (±)-trans-1,2-diaminocyclohexane. The MOGLS is formed by a 0.126 M methanolic solution of (1R,2R)-(+)-1,2-diaminocyclohexane L-tartrate and 1 equiv of concentrated hydrochloric acid. Nonreversible gelation of oxygenated and nitrogenated solvents occurs efficiently at low temperature. Several features make this system unique: (1) it is a multicomponent solution where each of the five components is required for the organogelation property; (2) the multicomponent organogelator liquid system (MOGLS) is formed by simple, small, and commercially available chiral building blocks dissolved in a well-defined solvent system (MeOH/HCl/H2O); (3) the chiral building blocks are easily amenable for further modifications in structure-property relationship studies; (4) the gelation phenomenon takes place efficiently at low temperature upon warming up the isotropic solution, conversely to the typical gel preparation protocol (gel formation upon cooling down the isotropic solution); (5) the formed organic gels are not thermoreversible in spite of the noncovalent interactions that hold the 3D-fibrillar network together.

I hope this article can help some friends in scientific research. I am very proud of our efforts over the past few months and hope to 1436-59-5, help many people in the next few years., Reference of 1436-59-5

Reference:
Chiral Catalysts,
Chiral catalysts – SlideShare