In an article, published in an article, once mentioned the application of 33100-27-5, Name is 1,4,7,10,13-Pentaoxacyclopentadecane,molecular formula is C10H20O5, is a conventional compound. this article was the specific content is as follows.category: chiral-catalyst
The use of the tripodal ligands tris[(N?-tert-butylureaylato)-N- ethyl]aminato ([H3buea]3-) and the sulfonamide-based N,N?,N?-[2,2?,2?-nitrilotris(ethane-2,1-diyl)]tris(2,4, 6-trimethylbenzene-sulfonamidato) ([MST]3-) has led to the synthesis of two structurally distinct In(III)-OH complexes. The first example of a five-coordinate indium(III) complex with a terminal hydroxide ligand, K[In IIIH3buea(OH)], was prepared by addition of In(OAc) 3 and water to a deprotonated solution of H6buea. X-ray diffraction analysis, as well as FTIR and 1H NMR spectroscopic methods, provided evidence for the formation of a monomeric In(III)-OH complex. The complex contains an intramolecular hydrogen bonding (H-bonding) network involving the In(III)-OH unit and [H3buea]3- ligand, which aided in isolation of the complex. Isotope labeling studies verified the source of the hydroxo ligand as water. Treatment of the [InIIIMST] complex with a mixture of 15-crown-5 ether and NaOH led to isolation of the complex [15-crown-5?NaI-(mu-OH)- InIIIMST], whose solid-state structure was confirmed using X-ray diffraction methods. Nuclear magnetic resonance studies on this complex suggest it retains its heterobimetallic structure in solution.
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