Brief introduction of 1806-29-7

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Sugar-modified biphenyl aromatics, preparation method and application thereof (by machine translation)

The invention relates to sugar-modified biphenyl aromatics, preparation method and application thereof. The compound of the structural formula is: M=0, R=R1 When, n=4 and 5; m=1, R=R2 When, n=3 and 4 its inclusion compound respectively in order to water-soluble sugar-modified two-biphenyl aromatics and terphenyl aromatic hydrocarbon macrocyclic, paraquat as separate objects and terphenyl emergence coprecipitation, part of the paraquat object is precipitated out, but two-biphenyl aromatic do not have this function. The water-soluble sugar modified two-biphenyl aromatics, terphenyl arenes with paraquat molecular molar ratio of 1:1. By fluorescence titration, found that the galactose-modified terphenyl aromatic hydrocarbon of paraquat of bonding capability most strong, in particular tetra-bonding constant as high as 108 . The method has simple operation, mild reaction conditions and the like, in order to remove the paraquat provides a new method. (by machine translation)

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Chiral Catalysts,
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More research is needed about 1806-29-7

Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Computed Properties of C12H10O2. In my other articles, you can also check out more blogs about 1806-29-7

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BIPHENOL ETHER COMPOUNDS

A compound having formula (I), wherein R represents C1-C18 alkyl, C5-C18 cycloalkyl, C3-C18 alkenyl or C3-C18 alkynyl; provided that, when -OR groups are in 2,2′-positions on benzene rings in formula (I), R is not methyl, ethyl, hexyl, octyl or allyl.

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Chiral Catalysts,
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Syntheses und NMR-Spektren phosphororganischer Antioxidantien und verwandter Verbindungen

The syntheses of various aliphatic, aromatic, sterically hindered, and cyclic organophosphorus compounds (phosphorous acid esters, esters chlorides and ester amides, hydrogen phosphites, phosphinates and phosphates) are reported, and general procedures for preparation are given.The compounds synthesized were investigated by means of 31P-, 1H- and 13C-n.m.r. spectroscopy, and the chemical shifts measured are listed.

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A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 1806-29-7, Name is 2,2-Biphenol, molecular formula is C12H10O2. In a Patent£¬once mentioned of 1806-29-7, Computed Properties of C12H10O2

Method for joint production of 3 – methyl – 1, 5 – pentanediol and C1 – C6 alkoxide method (by machine translation)

The present invention provides a production of 3 – methyl – 1, 5 – pentanediol and C1 – C6 alkoxide method, comprises the following steps: 1) the 3 – methyl – 3 – butene – 1 – ol and C1 – C6 acid esterification reaction, is contained and C1 – C6 acid – 3 – methyl – 3 – butene – 1 – alcohol ester of the esterification product; 2) in the step 1) with the esterification product containing CO and H2 The gas hydroformylation reaction; 3) in the step 2) of the hydrogenolysis reaction to the reaction product, to obtain 3 – methyl – 1, 5 – pentanediol and C1 – C6 alcohol. The invention firstly esterification re-hydroformylation, hydrogenation process route, to avoid 3 – methyl – 3 – butene – 1 – ol directly hydroformylation, it is beneficial to avoid direct hydroformylation reaction generated by the side reaction of the inevitable; at the same time, the use of the process of the invention can also be co line C1 – C6 alcohol (for example ethanol). (by machine translation)

Sometimes chemists are able to propose two or more mechanisms that are consistent with the available data.Computed Properties of C12H10O2, If a proposed mechanism predicts the wrong experimental rate law, however, the mechanism must be incorrect.Welcome to check out more blogs about 1806-29-7, in my other articles.

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Chiral Catalysts,
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NOVEL MONOPHOSPHITE COMPOUNDS HAVING A METHYL GROUP

Novel monophosphite compounds having a methyl group, and a process for preparing these compounds, which are especially suitable for use as ligands in hydroformylation reactions.

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Chiral Catalysts,
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COMPOSITION AND CURED ARTICLE COMPRISING INORGANIC PARTICLES AND EPOXY COMPOUND HAVING ALKOXYSILYL GROUP, USE FOR SAME, AND PRODUCTION METHOD FOR EPOXY COMPOUND HAVING ALKOXYSILYL GROUP

There is provided a composition including an alkoxysilylated epoxy compound, a composition of which exhibits good heat resistance properties, low CTE and high glass transition temperature or Tg-less and not requiring a separate coupling agent, and inorganic particles, a cured product formed of the composition, and a use of the cured product. An epoxy composition including an alkoxysilylated epoxy compound and inorganic particles, an epoxy composition including an epoxy compound, inorganic particles and a curing agent, a cured product of the composition, and a use of the composition are provided. Since chemical bonds may be formed between the alkoxysilyl group and the inorganic particles and between the alkoxysilyl groups, a composition of the composition including the alkoxysilylated epoxy compound and the inorganic particles exhibits improved heat resistance properties, decreased CTE, and increased glass transition temperature or Tg less.

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Chiral Catalysts,
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Rhodium catalysed asymmetric hydroformylation with chiral diphosphite ligands

Chiral diphosphites have been synthesised starting from 1,2:5,6-diisopropylidene-D-mannitol, L-alpha,alpha,alpha,alpha,-tetramethyla-1,3-dioxolan-4,5-dimethanol and L-diethyltertrate. The diols react in moderate to good yields with 2,2′-bisphenoxyphosphorus chloride and 4,4’6,6′,-tetra-t-butyl-2,2′-bisphenoxyphosphorus chloride (32-92%) to the corresponding chiral diphosphites. The compounds all exhibit C2 symmetry and have been used as ligands in the rhodium catalysed asymmetric hydroformylation of styrene. The catalytic activity of the diphosphites strongly depends on the bulkynes of the ligand. With a bulky ligand enantiomeric excesses up till 20% have been obtained under mild reaction conditions (25-40C, 40 bar syngas). It was found that both enantiomeric excess and regioselectivity to the branched aldehyde strongly depend on the hydroformylation reaction conditions.

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InCl3 and ZrCl4 catalyzed regioselective reaction of 2,2?-dihydroxybiphenyl with terminal alkynes: synthesis of new dibenzo[d,f][1,3]dioxepines

The regioselective reaction of 2,2?-dihydroxybiphenyl with terminal alkynes was found to be rapidly catalyzed by InCl3 and ZrCl4. The chemoselectivity of catalysts and alkynes for biphenol over water, together with the reaction mechanism are discussed in details.

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Archives for Chemistry Experiments of 1806-29-7

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Bronsted acid-catalyzed synthesis of pyrans via a formal [3+3] cycloaddition

Bronsted acids catalyze the addition of enolizable ss-keto esters to alpha,ss-unsaturated aldehydes leading to substituted 2H-pyrans in good yields under mild conditions via a formal [3+3] cycloaddition.

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The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.1806-29-7, Name is 2,2-Biphenol, molecular formula is C12H10O2. In a Article£¬once mentioned of 1806-29-7, category: chiral-catalyst

Synthesis, structural characterization and dielectric behavior of new oxime-cyclotriphosphazene derivatives

The cyclotriphosphazene compound (2) bearing formyl groups as side groups was obtained from the reaction of 2,2-Dichloro-4,4,6,6-bis[spiro(2?,2?-dioxy-1?,1?-biphenylyl)]cyclotriphosphazene (1) with 4-hydroxy-3-methoxybenzaldehyde in the presence K2CO3 in tetrahydrofuran. Oxime-cyclotriphosphazene compound (3) was synthesized from the reaction of compound 2 with hydroxylamine hydrochloride in pyridine. The synthesized oxime-phosphazene compound (3) was reacted with alkyl and acyl halides. As a results, the cyclotriphosphazene compounds (1-10) bearing oxime ether and ester as side groups were obtained. The chemical structures of these compounds (1-10) were determined by elemental analysis, FT-IR, 1H, 13C and 31P NMR spectroscopic methods. Dielectric constant, dielectric loss factors and conductivity properties of cyclotriphosphazene compounds were measured over the frequency range from 100 Hz to 2 kHz at 25C and compared with each other. It is found that ester substituted cyclotriphosphazenes have higher dielectric constant. Our study suggests that these phosphazenes promising candidate materials in multifunctional optoelectronic devices.

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Chiral Catalysts,
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