HPLC of Formula: 542-58-5. The mechanism of aromatic electrophilic substitution of aromatic heterocycles is consistent with that of benzene. Compound: 2-Chloroethyl acetate, is researched, Molecular C4H7ClO2, CAS is 542-58-5, about Effects of polar β-substituents in the gas-phase pyrolysis of ethyl acetate esters. Author is Chuchani, Gabriel; Martin, Ignacio; Hernandez A., Jose A.; Rotinov, Alexandra; Fraile, German; Bigley, David B..
Kinetic data for the pyrolysis of AcOCH2CH2R (I; R = NMe2, OMe, SMe, Cl, F, CN) were obtained and discussed along with literature data for addnl. I. The effects of R fell into one of 3 classes. A linear correlation with σ constants was obtained for several -I electron-withdrawing groups. A small amount of anchimeric assistance was proposed in the pyrolysis of the I (R = SMe). The data were consistent with a transition state where the Cα-O bond polarization is the rate-determining process.
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