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The values of the 1J(199Hg199Hg) coupling constant in solution of the asymmetric dimercury(2+) complexes with the stoichiometries Hg22+/18-crown-6 and Hg22+/18-crown-6/15-crown-5 are 220 300 and 284 100 Hz, respectively, representing the largest scalar couplings measured.
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