Discovery of cis-Cyclohexane-1,2-diamine

The proportionality constant is the rate constant for the particular unimolecular reaction. the reaction rate is directly proportional to the concentration of the reactant. I hope my blog about 1436-59-5 is helpful to your research., Electric Literature of 1436-59-5

Electric Literature of 1436-59-5, Catalysts are substances that increase the reaction rate of a chemical reaction without being consumed in the process. 1436-59-5, Name is cis-Cyclohexane-1,2-diamine, molecular formula is C6H14N2. In a Article,once mentioned of 1436-59-5

In the absence of a metal ion, racemic trans-1,2-diaminocyclohexane (trans-(±)DCH) reacts with acetylacetone (acacH) (1:2.5 mole ratio) to form the bisoxoenamine condensation product, boe (1). CoCl2·6H2O and Co(ClO4)2·6H2O each react with trans-(±)DCH in air to give complexes containing the oxidised Co(III) ion, [Co((±)DCH)3]3+, which does not subsequently react with added acacH to give a Schiff base complex. Mixtures of complexes are obtained from one-pot reactions involving trans-(±)DCH, a simple Co(II) salt and acacH (1:1:2.5 mole ratio). When CoCl2·6H2O is used, the mixed-ligand Co(II) complex [Co((±)DCH)Cl2] (4) precipitates first and, after a period of weeks, the Co(II) complex (diazH)2[CoCl4] (5) (diazH+ is a diazepinium cation), the Co(II) complex [Co(boe)Cl2]n (6) and the Co(III) complex [Co(acac)3] (7), co-crystallise from the mother liquor. Using Co(ClO4)2·6H2O in the reaction with trans-(±)DCH and acacH also gives a mixture of products. Complexes 7, the Co(II) complex [Co2(acac)4(H2O)2][Co(acac)(H 2O)4]ClO4·EtOH (8) and the Co(III) complex [Co(acac)2(±)DCH]ClO4 (9) co-crystallise. Complexes 1, 5, 7, 8 and 9 were characterised using X-ray crystallography. The major difference between using CoCl2·6H2O and Co(ClO4)2·6H2O in reactions involving (±)DCH and acacH is that no DCH/acacH condensation products are identified in the product mixtures when the perchlorate salt is employed.

The proportionality constant is the rate constant for the particular unimolecular reaction. the reaction rate is directly proportional to the concentration of the reactant. I hope my blog about 1436-59-5 is helpful to your research., Electric Literature of 1436-59-5

Reference:
Chiral Catalysts,
Chiral catalysts – SlideShare