Let¡¯s face it, organic chemistry can seem difficult to learn, Product Details of 17455-13-9, Especially from a beginner¡¯s point of view. Like 17455-13-9, Name is 1,4,7,10,13,16-Hexaoxacyclooctadecane, molecular formula is C6H8O6, belongs to Benzisoxazole compound. In a document, author is Kotani, Shunsuke, introducing its new discovery.
A hypervalent silicon complex between trichlorosilane and a chiral phosphine oxide acts as an effective Lewis acid mediator that successfully promotes highly enantioselective cross-aldol reactions between two aldehydes. The high yielding transformation is realized with the assistance of triisobutylamine, which does not decompose trichlorosilane but rather converts the aldol donor into the silyl enol ether that undergoes the enantioselective cross-aldol reaction with a second aldehyde in combination with the chiral phosphine oxide catalyst.
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Reference:
Chiral Catalysts,
,Chiral catalysts – SlideShare