Extended knowledge of (R)-4-Hydroxydinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepine 4-oxide

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In an article, published in an article, once mentioned the application of 39648-67-4, Name is (R)-4-Hydroxydinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepine 4-oxide,molecular formula is C20H13O4P, is a conventional compound. this article was the specific content is as follows.name: (R)-4-Hydroxydinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepine 4-oxide

The phosphate ester 1,1?-binaphthyl-2,2?-diyl-phosphate shows an intense fluorescence of the binaphthyl moiety. In the complex 1,1?-binaphthyI-2,2?-diyl-phosphato-pentaammine-cobalt(III) this emission is quenched by excited state electron transfer to Co(III). As a consequence the phosphate ester undergoes an oxidative cleavage while Co(III) is reduced to Co(II) with phi=0.023phi0.002 at lambdairr=313 nm. WILEY-VCH Verlag GmbH, 1998.

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Reference:
Chiral Catalysts,
Chiral catalysts – SlideShare