An article , which mentions 250285-32-6, molecular formula is C27H37ClN2.250285-32-6, The compound – 1,3-Bis(2,6-diisopropylphenyl)imidazolium chloride played an important role in people’s production and life.
A Mechanistically and Operationally Simple Route to Metal?N-Heterocyclic Carbene (NHC) Complexes
We have been puzzled by the involvement of weak organic and inorganic bases in the synthesis of metal?N-heterocyclic carbene (NHC) complexes. Such bases are insufficiently strong to permit the presumed required deprotonation of the azolium salt (the carbene precursor) prior to metal binding. Experimental and computational studies provide support for a base-assisted concerted process that does not require free NHC formation. The synthetic protocol was found applicable to a number of transition-metal- and main-group-centered NHC compounds and could become the synthetic route of choice to form M?NHC bonds.
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Chiral Catalysts,
Chiral catalysts – SlideShare