Final Thoughts on Chemistry for 14098-44-3

In an article, published in an article, once mentioned the application of 14098-44-3, Name is Benzo-15-crown-5,molecular formula is C14H20O5, is a conventional compound. this article was the specific content is as follows.Safety of Benzo-15-crown-5

Binuclear and mononuclear di-eta5-cyclopentadienylniobium chemistry: a new insight. Crystal and molecular structure of –+

A mononuclear di-eta5-cyclopentadienylniobium complex Cp2NbH2Na (I) has been found to be a by-product of the reaction of Cp2NbCl2 with NaH, the principal products being (eta5 : eta1-C5H4)2Cp2Nb2H2 (II) in THF and (eta5 : eta5-C5H4C5H4)Cp2Nb2(mu-H)2 (III) in DME.Cp2NbH2Na was also obtained by reaction of Cp2NbH3 or the mixture Cp2NbBH4 + Et3N with NaH.Crystal and molecular structure of –+ (Ia) (B15C5 = benzo-15-crown-5) was established by an X-ray diffraction study (4208 reflections, R = 0.022; monoclinic, at -120 deg C, a 17.345(3), b 11.742(3), c 22.965(5) Angstroem, beta 98.52(1) degree, Z = 8, space gr oup C2/c).The structural data indicate substantial ionic character of the (Cp2NbH2)-…(Na*B15C5)+ interaction in the solid.

Do you like my blog? If you like, you can also browse other articles about this kind. Safety of Benzo-15-crown-5. Thanks for taking the time to read the blog about 14098-44-3

Reference£º
Chiral Catalysts,
Chiral catalysts – SlideShare