Chemistry is the science of change. But why do chemical reactions take place? Why do chemicals react with each other? The answer is in thermodynamics and kinetics.In a document type is Article, the author is Dranka, Maciej and a compound is mentioned, 33100-27-5, 1,4,7,10,13-Pentaoxacyclopentadecane, introducing its new discovery. 33100-27-5
Coordination Abilities of 4,5-Dicyano-2-(trifluoromethyl)imidazolate Anion toward Sodium Cation: Structural and Spectroscopic Studies of Solid and Liquid Glyme-Solvated Electrolyte Systems
Comprehensive structural analysis of sodium 4,5-dicyano-2-(trifluoromethyl)imidazolate (NaTDI) solvates with glymes (1-4), tetrahydrofuran, and crown ethers has been performed. Several structural motifs obtained from single-crystal X-ray analysis of complementary series of crystalline adducts with varying O:Na ratios were correlated with spectroscopic and thermal data to provide new information about the coordination ability of heterocyclic anions toward sodium cations. Presented results provide a basis for developing models of poly(ethylene oxide) electrolytes and liquid systems for sodium ion battery electrolytes. We have found a wide variety of anion-cation coordination types which allow us to compare them with analogous lithium solvates in terms of Brown’s valence-matching principle and Lewis acid strength (Sa) parameters. Noticed aggregation modes of sodium salts confirm the occurrence of a solvate disproportionation conductivity mechanism at high salt concentrations which can be used for developing new heterocyclic salt systems for sodium batteries.
But sometimes, even after several years of basic chemistry education, it is not easy to form a clear picture on how they govern reactivity! Read on for other articles about 33100-27-5!, 33100-27-5
Reference£º
Chiral Catalysts,
Chiral catalysts – SlideShare